For the operando XAS measurements of electrochemical reactions, the electrochemical cell including working, counter, and reference electrodes were developed [1, 2]. The Fe L-edge XAS spectra of aqueous iron sulfate solutions were successfully measured at different potentials with a scan rate of 100 mV/s. The mechanisms of the Fe redox reactions with the change in valence of Fe ions were discussed by correlating the results of cyclic voltammetry with the same scan rates.
- M. Nagasaka et al., J. Phys. Chem. C 117, 16343 (2013).
- M. Nagasaka et al., Rev. Sci. Instrum. 85, 104105 (2014).
